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Issue 14, 2003
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The first asymmetric synthesis of trialkyl phosphates on the basis of dynamic kinetic resolution in the phosphite method using a chiral source in a catalytic manner

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Abstract

The first asymmetric synthesis of trialkyl phosphates having stereogenic phosphorus atoms on the basis of dynamic kinetic resolution using a chiral source in a catalytic manner; achieved through the stereospecific oxidation of a trialkyl phosphite enantioselectively obtained by the condensation of a racemic unsymmetrically substituted dialkyl phosphorochloridite and an alcohol using a chiral amine as a catalytic promoter.

Graphical abstract: The first asymmetric synthesis of trialkyl phosphates on the basis of dynamic kinetic resolution in the phosphite method using a chiral source in a catalytic manner

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Publication details

The article was received on 15 Apr 2003, accepted on 28 May 2003 and first published on 13 Jun 2003


Article type: Communication
DOI: 10.1039/B304163H
Citation: Chem. Commun., 2003,0, 1704-1705
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    The first asymmetric synthesis of trialkyl phosphates on the basis of dynamic kinetic resolution in the phosphite method using a chiral source in a catalytic manner

    Y. Hayakawa, M. Hyodo, K. Kimura and M. Kataoka, Chem. Commun., 2003, 0, 1704
    DOI: 10.1039/B304163H

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