Issue 9, 2003
From the journal:

Chemical Communications

Stereoselective formation of dinuclear complexes with anomalous CD spectra†

Shane G. Telfer,*a   Reiko Kuroda*ab  and  Tomohiro Satoa  

* Corresponding authors

a JST ERATO Kuroda Chiromorphology Project, Park Bldg., 4-7-6 Komaba, Meguro-ku, Tokyo 153-0041, Japan
E-mail: shane.telfer@chiromor2.erato.rcast.u-tokyo.ac.jp
Fax: +81 3 5465 0104
Tel: +81 3 5465 0104

b Graduate School of Arts and Sciences, University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan
E-mail: ckuroda@mail.ecc.u-tokyo.ac.jp
Fax: +81 3 5454 6600
Tel: +81 3 5454 6600

Abstract

A novel chiral tetradentate Schiff base ligand forms dinuclear Λ,Λ-[M2L2Cl2]2+ complexes with high diastereoselectivity; the complexes exhibit anomalous CD spectra due to exciton coupling of chromophores located on different metal centres.

Graphical abstract: Stereoselective formation of dinuclear complexes with anomalous CD spectra

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Article information

DOI
https://doi.org/10.1039/B301267K
Article type
Communication
Submitted
03 Feb 2003
Accepted
13 Mar 2003
First published
27 Mar 2003

Chem. Commun., 2003, 1064-1065

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Stereoselective formation of dinuclear complexes with anomalous CD spectra

S. G. Telfer, R. Kuroda and T. Sato, Chem. Commun., 2003, 1064 DOI: 10.1039/B301267K

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