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Issue 6, 2003
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Cooperative effects in the complexation of anions and Lewis bases by a heteronuclear bifunctional Lewis acid

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Abstract

As shown by the complexation of electron-rich substrates to the heteronuclear bifunctional Lewis acid bis(μ-1,8-naphthalenediyl)(μ-chloride)methyltin-chlorogallium (1), the primary Lewis acidic site of this molecule is the triorganotin chloride moiety whose electron deficiency is enhanced through partial abstraction of its chloride ligand by the neighbouring gallium centre.

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Publication details

The article was received on 05 Dec 2002, accepted on 28 Jan 2003 and first published on 14 Feb 2003


Article type: Communication
DOI: 10.1039/B212127A
Chem. Commun., 2003, 712-713

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    Cooperative effects in the complexation of anions and Lewis bases by a heteronuclear bifunctional Lewis acid

    J. D. Hoefelmeyer and F. P. Gabbaï, Chem. Commun., 2003, 712
    DOI: 10.1039/B212127A

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