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Issue 2, 2003
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Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10− to [Ni8(cit)6(OH)2]10−

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Abstract

The role of temperature in the formation of high nuclearity nickel(II) citrate spin clusters is explored, revealing how changes in structure and hence magnetic properties can be triggered through desolvation and ligand reorganisation.

Graphical abstract: Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10− to [Ni8(cit)6(OH)2]10−

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Publication details

The article was received on 23 Oct 2002, accepted on 21 Nov 2002 and first published on 10 Dec 2002


Article type: Communication
DOI: 10.1039/B210327C
Chem. Commun., 2003, 230-231

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    Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10− to [Ni8(cit)6(OH)2]10−

    M. Murrie, D. Biner, H. Stœckli-Evans and H. U. Güdel, Chem. Commun., 2003, 230
    DOI: 10.1039/B210327C

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