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Issue 7, 2003
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Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes

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Abstract

The first examples of the PN-directed dilithiation of (N-methoxycarbonyl)phosphazenes in the Cα and Cortho to the phosphorus, and the use of these dianions in the formation of tri- and tetra-substituted olefins through stereospecific thermolysis of a new type of isolable bicyclic 1,2-oxaphosphetanes are described.

Graphical abstract: Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes

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Article information


Submitted
23 Dec 2002
Accepted
14 Feb 2003
First published
03 Mar 2003

Chem. Commun., 2003, 856-857
Article type
Communication

Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes

J. García-López, E. Peralta-Pérez, A. Forcén-Acebal, S. García-Granda and F. López-Ortiz, Chem. Commun., 2003, 856
DOI: 10.1039/B212708C

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