Issue 11, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

1,3,5-Tris(4-aminophenyl)benzene derivatives: design, synthesis via nickel-catalysed aromatic amination and electrochemical properties

Christophe Desmarets,a   Raphaël Schneider,a   Yves Fort*a  and  Alain Walcariusb  

* Corresponding authors

a Synthèse Organique et Réactivité, UMR CNRS 7565, Université Henri Poincaré, Nancy I, Faculté des Sciences, BP 239, 54506 Vandoeuvre les Nancy Cedex, France
E-mail: Yves.Fort@sor.uhp-nancy.fr

b Laboratoire de Chimie Physique et Microbiologie pour l'Environnement, UMR 7564, CNRS-Université Henri Poincaré, Nancy I, 405, rue de Vandoeuvre, 54600 Villers-les-Nancy, France
E-mail: walcariu@lcpe.cnrs-nancy.fr

Abstract

Nickel-catalysed polycondensation reactions of 1,3,5-tris(p-chlorophenyl)benzene with secondary cyclic and acyclic amines afforded the corresponding triarylamines in good yields. Oxidation of these materials creates dications diradicals that are stable over several minutes at room temperature. The electronic and magnetic properties of these dications were investigated by cyclic voltammetry, chronoamperometry, UV–VIS and EPR spectroscopy.

Graphical abstract: 1,3,5-Tris(4-aminophenyl)benzene derivatives: design, synthesis via nickel-catalysed aromatic amination and electrochemical properties

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Article information

DOI
https://doi.org/10.1039/B206689K
Article type
Paper
Submitted
10 Jul 2002
Accepted
09 Sep 2002
First published
11 Oct 2002

J. Chem. Soc., Perkin Trans. 2, 2002, 1844-1849

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1,3,5-Tris(4-aminophenyl)benzene derivatives: design, synthesis via nickel-catalysed aromatic amination and electrochemical properties

C. Desmarets, R. Schneider, Y. Fort and A. Walcarius, J. Chem. Soc., Perkin Trans. 2, 2002, 1844 DOI: 10.1039/B206689K

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