Effects of magnesium ion on kinetic stability and spin distribution of phenoxyl radical derived from a vitamin E analogue: mechanistic insight into antioxidative hydrogen-transfer reaction of vitamin E†
Abstract
The phenoxyl radical 1˙ of a
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* Corresponding authors
a
Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences, Inage-ku, Chiba 263-8555, Japan
E-mail:
nakanis@nirs.go.jp
Fax: +81-43-255-6819
Tel: +81-43-206-3131
b Division of Organic Chemistry, National Institute of Health Sciences, Setagaya-ku, Tokyo 158-8501, Japan
c Department of Applied Chemistry, Shibaura Institute of Technology, Minato-ku, Tokyo 108-8548, Japan
d Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation, Suita, Osaka 565-0871, Japan
e Division of Organic and Bioorganic Chemistry, Kyoritsu College of Pharmacy, Minato-ku, Tokyo 105-8512, Japan
f Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan
g Department of Organic and Medicinal Chemistry, Graduate School of Pharmaceutical Sciences, Nagoya City University, Mizuho-ku, Nagoya 467-8603, Japan
The phenoxyl radical 1˙ of a
I. Nakanishi, K. Fukuhara, T. Shimada, K. Ohkubo, Y. Iizuka, K. Inami, M. Mochizuki, S. Urano, S. Itoh, N. Miyata and S. Fukuzumi, J. Chem. Soc., Perkin Trans. 2, 2002, 1520 DOI: 10.1039/B205380B
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