Issue 7, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation

Luigi R. Nassimbeni*a  and  Hong Sua  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa

Abstract

The inclusion compounds of binaphthol with three isomers of xylidine have been studied in terms of their structures and infra-red spectra. Competition experiments show that the selectivity of enclathration follows the trend: 2,6-xylidine > 2,3-xylidine ≈ 3,5-xylidine. The kinetics of desolvation have been analysed and the activation energies established.

Graphical abstract: Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation

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Article information

DOI
https://doi.org/10.1039/B204190C
Article type
Paper
Submitted
06 Dec 2001
Accepted
30 Apr 2002
First published
31 May 2002

J. Chem. Soc., Perkin Trans. 2, 2002, 1246-1250

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Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation

L. R. Nassimbeni and H. Su, J. Chem. Soc., Perkin Trans. 2, 2002, 1246 DOI: 10.1039/B204190C

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