Issue 17, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

On the steric acceleration of ene reactions

Nandeo Choony,a   Nikolai Kuhnert,a   Peter G. Sammes,*a   Graham Smitha  and  Robert W. Wardb  

* Corresponding authors

a Department of Chemistry, School of Physics and Chemistry, UniS, Guildford, Surrey, UK

b GlaxoSmithKline Pharmaceuticals, New Frontiers Science Park, Third Avenue, Harlow, Essex, UK

Abstract

Steric buttressing, using the removable trityl group as a protecting group for substituted allylamines, is used to effect selective cycloadditions and uncatalysed ene reactions under remarkably mild conditions.

Graphical abstract: On the steric acceleration of ene reactions

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Article information

DOI
https://doi.org/10.1039/B204778K
Article type
Paper
Submitted
16 May 2002
Accepted
26 Jun 2002
First published
05 Aug 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 1999-2005

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On the steric acceleration of ene reactions

N. Choony, N. Kuhnert, P. G. Sammes, G. Smith and R. W. Ward, J. Chem. Soc., Perkin Trans. 1, 2002, 1999 DOI: 10.1039/B204778K

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