[NiL]3[BTC]2·14H2O [L = 3,10-bis(2-ethyl)-1,3,5,8,10,12-hexaazacyclotetradecane, BTC = 1,3,5-benzenetricarboxylate]: synthesis, structure and unique selective guest molecule absorption properties†
Abstract
Reaction of 1,3,5-benzenetricarboxylate with a macrocyclic Ni(II) complex leads to a porous metal-organic framework, which displays a high selectivity for