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Issue 10, 2002
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Syntheses, structures, electrochemistry and magnetic properties of chain-like dicyanamide manganese(iii) and iron(iii) complexes with salen ligand

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Abstract

Two dicyanamide (dca) MIII complexes with salen ligand, [MnIII(salen)(dca)]n (1) and [FeIII(salen)(dca)]n (2), were synthesized and characterized. X-Ray diffraction analyses revealed the two complexes have a similar one-dimensional zig-zag chain structure constructed by μ1,5-dca bridge. Magnetic susceptibility measurements indicate the presence of antiferromagnetic interactions between two intra-chain high-spin MnIII ions and between two intra-chain low-spin FeIII ions via the dca bridge. The electrochemical properties of the two complexes were studied by cyclic voltammetry.

Graphical abstract: Syntheses, structures, electrochemistry and magnetic properties of chain-like dicyanamide manganese(iii) and iron(iii) complexes with salen ligand

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Article information


Submitted
24 Jan 2002
Accepted
03 May 2002
First published
21 Aug 2002

New J. Chem., 2002,26, 1397-1401
Article type
Paper

Syntheses, structures, electrochemistry and magnetic properties of chain-like dicyanamide manganese(III) and iron(III) complexes with salen ligand

Q. Shi, R. Cao, X. Li, J. Luo, M. Hong and Z. Chen, New J. Chem., 2002, 26, 1397
DOI: 10.1039/B200907B

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