Issue 4, 2002
From the journal:

New Journal of Chemistry

Novel silver(I) complexes derived from tetrakis(methylthio)tetrathiafulvalene and bis(ethylenedithio)tetrathiafulvalene with 3D and 1D structures

Chunyang Jia,a   Deqing Zhang,*a   Cai-Ming Liu,a   Wei Xu,a   Huaiming Hua  and  Daoben Zhu*a  

* Corresponding authors

a Organic Solids Laboratory, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: dqzhang@infoc3.icas.ac.cn

Abstract

Novel silver(I) complexes 1 and 2 derived from tetrakis(methylthio)tetrathiafulvalene (TMTTTF) and bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF), respectively, were prepared by the self-assembly approach. Their crystal structures were determined. Complex 1 shows a three-dimensional structure with an unprecedented 4.16-net porous inorganic layer of silver nitrate. In complex 2, silver(I) is coordinated to the BEDT-TTF+ cation and an extended 1D “zig-zag” chain is formed. The electrical conducting properties of complex 1 (after oxidation by iodine) and complex 2 were investigated.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B108823H
Article type
Paper
Submitted
01 Oct 2001
Accepted
03 Dec 2001
First published
15 Mar 2002

New J. Chem., 2002,26, 490-494

Permissions

Request permissions

Novel silver(I) complexes derived from tetrakis(methylthio)tetrathiafulvalene and bis(ethylenedithio)tetrathiafulvalene with 3D and 1D structures

C. Jia, D. Zhang, C. Liu, W. Xu, H. Hu and D. Zhu, New J. Chem., 2002, 26, 490 DOI: 10.1039/B108823H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements