The zero-field splitting parameters of triplet nitreno-s-triazines indicate that triplet and singlet nitrenes have sp3 and sp2 hybridization of the nitrene centres, respectively.
Zero-field splitting parameters of triplet nitreno-s-triazines: a new insight into the geometry of the nitrene centres of triplet and singlet nitrenes
S. V. Chapyshev, Mendeleev Commun., 2002, 12, 227 DOI: 10.1070/MC2002v012n06ABEH001683
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