Formation of an optically active 2-phenyl[1,2,4]triazolo[1,5-a]pyrimidine derivative in the reaction of (+)-3-carene-derived β-chlorovinylketone with benzylidene aminoguanidine

Sergey A. Popov; Tatyana V. Rybalova; Yury V. Gatilov; Alexey V. Tkachev

doi:10.1070/MC2002v012n06ABEH001678

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Formation of an optically active 2-phenyl[1,2,4]triazolo[1,5-a]pyrimidine derivative in the reaction of (+)-3-carene-derived β-chlorovinylketone with benzylidene aminoguanidine

Sergey A. Popov,^a Tatyana V. Rybalova,^a Yury V. Gatilov^a and Alexey V. Tkachev^b

Author affiliations

^a N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation, Prospekt Akademika Lavrent'eva, 9, Novosibirsk, Russian Federation

^b Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation, ul. Pirogova, 2, Novosibirsk, Russian Federation

Abstract

The treatment of a seco-carane-type β-chlorovinyl ketone with benzylidene aminoguanidine in boiling methanol in the presence of sodium bicarbonate results in the formation of a substituted 2-phenyl[1,2,4]triazolo[1,5-a]pyrimidine.

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DOI: https://doi.org/10.1070/MC2002v012n06ABEH001678
Article type: Paper
Submitted: 31 Oct 2002

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Mendeleev Commun., 2002,12, 226-227

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Formation of an optically active 2-phenyl[1,2,4]triazolo[1,5-a]pyrimidine derivative in the reaction of (+)-3-carene-derived β-chlorovinylketone with benzylidene aminoguanidine

S. A. Popov, T. V. Rybalova, Y. V. Gatilov and A. V. Tkachev, Mendeleev Commun., 2002, 12, 226 DOI: 10.1070/MC2002v012n06ABEH001678

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Mendeleev Communications

Formation of an optically active 2-phenyl[1,2,4]triazolo[1,5-a]pyrimidine derivative in the reaction of (+)-3-carene-derived β-chlorovinylketone with benzylidene aminoguanidine

Abstract

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Formation of an optically active 2-phenyl[1,2,4]triazolo[1,5-a]pyrimidine derivative in the reaction of (+)-3-carene-derived β-chlorovinylketone with benzylidene aminoguanidine

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