Issue 4, 2002
From the journal:

Mendeleev Communications

Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations

Remir G. Kostyanovsky,*a   Volker Schurig,b   Oliver Trapp,b   Konstantin A. Lyssenko,c   Boris B. Averkiev,c   Gul'nara K. Kadorkina,a   Alexander V. Prosyanikd  and  Vasily R. Kostyanovskya  

* Corresponding authors

a N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation, ul. Kosygina, 4, Moscow, Russian Federation
E-mail: kost@center.chph.ras.ru

b Institut fuer Organische Chemie, Eberhard Karls Universitaet Tuebingen, Tuebingen, Germany, Auf der Morgenstelle 18, Tuebingen, Germany

c A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation, ul. Vavilova, 28, Moscow, Russian Federation

d Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine, 8 Gagarina prosp., Dnepropetrovsk, Ukraine

Abstract

The resolution of enantiomers by chiral chromatography and the determination of nitrogen inversion activation parameters by dynamic chromatography have been carried out for aziridines 1–3; the structures of aziridines 4–7 have been studied; the complete diastereomeric transformation of (S,R)-(+)-8a into (R,R)-(–)-8b has been performed, and the conglomerate of high-melting diastereomer (±)-9 has been found.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1070/MC2002v012n04ABEH001612
Article type
Paper
Submitted
03 Jun 2002

Mendeleev Commun., 2002,12, 137-140

Permissions

Request permissions

Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations

R. G. Kostyanovsky, V. Schurig, O. Trapp, K. A. Lyssenko, B. B. Averkiev, G. K. Kadorkina, A. V. Prosyanik and V. R. Kostyanovsky, Mendeleev Commun., 2002, 12, 137 DOI: 10.1070/MC2002v012n04ABEH001612

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements