Issue 4, 2002
From the journal:

Journal of Materials Chemistry

Alain Pénicaud,*a   Olinda Y. Carreón,a   Aurélie Perrier,a   David J. Watkinb  and  Claude Coulona  

* Corresponding authors

a Centre de Recherche Paul Pascal, UPR 8641 CNRS, Université de Bordeaux-I, Av. Schweitzer, Pessac, France
E-mail: penicaud@crpp.u-bordeaux.fr

b Chemical Crystallography Laboratory, Oxford University, 9 Parks Road, Oxford, UK

Abstract

Cocrystallization of C60 and biphenyl affords neutral mixed single crystals, which present close compact arrays of C60 molecules and vacant sites. Intercalation with potassium at low temperature (80 °C) affords a new, ternary, fulleride salt. Additionally, a simple model has been developed to describe the kinetics of intercalation.

Graphical abstract: Supramolecular fullerene chemistry: synthesis, crystal structure and potassium intercalation of [(C60)][(C6H5)2]

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Article information

DOI
https://doi.org/10.1039/B106580G
Article type
Paper
Submitted
23 Jul 2001
Accepted
03 Dec 2001
First published
18 Mar 2002

J. Mater. Chem., 2002,12, 913-918

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Supramolecular fullerene chemistry: synthesis, crystal structure and potassium intercalation of [(C60)][(C6H5)2]

A. Pénicaud, O. Y. Carreón, A. Perrier, D. J. Watkin and C. Coulon, J. Mater. Chem., 2002, 12, 913 DOI: 10.1039/B106580G

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