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Issue 4, 2002
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Abstract

Cocrystallization of C60 and biphenyl affords neutral mixed single crystals, which present close compact arrays of C60 molecules and vacant sites. Intercalation with potassium at low temperature (80 °C) affords a new, ternary, fulleride salt. Additionally, a simple model has been developed to describe the kinetics of intercalation.

Graphical abstract: Supramolecular fullerene chemistry: synthesis, crystal structure and potassium intercalation of [(C60)][(C6H5)2]

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Article information


Submitted
23 Jul 2001
Accepted
03 Dec 2001
First published
18 Mar 2002

J. Mater. Chem., 2002,12, 913-918
Article type
Paper

Supramolecular fullerene chemistry: synthesis, crystal structure and potassium intercalation of [(C60)][(C6H5)2]

A. Pénicaud, O. Y. Carreón, A. Perrier, D. J. Watkin and C. Coulon, J. Mater. Chem., 2002, 12, 913
DOI: 10.1039/B106580G

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