Issue 6, 2002
From the journal:

Green Chemistry

Clean synthesis of F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols

Takumi Taniguchi,a   Eiji Hayashib  and  Taizo Ono*b  

* Corresponding authors

a Polymer Electrolyte Group, TOYOTA Central Research & Development Laboratories, 41-1, Yokomichi, Nagakute, Nagakute-cho, Aichi-gun, Japan
E-mail: takumi@taniguchi.tec.toyota.co.jp

b Molecular Structure Design Group (MOSTG), Institute for Structural and Engineering Materials, National Institutes of Advanced Industrial Science and Technology (AIST), 2266-98, Anagahora, Shimoshidami, Moriyama-ku, Nagoya, Japan
E-mail: t.ono@aist.go.jp

Abstract

The addition reactions of F-carboxylic acids to terminal and cyclic olefins and of F-alkanoyl halides to cyclic ethers has been found to be useful for preparing F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols, respectively. Both types of reaction can be performed under solvent-free conditions and no accompanying by-products are formed; in some cases a 100% atom efficiency was achieved.

Graphical abstract: Clean synthesis of F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols

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Article information

DOI
https://doi.org/10.1039/B207215G
Article type
Paper
Submitted
23 Jul 2002
First published
21 Oct 2002

Green Chem., 2002,4, 595-598

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Clean synthesis of F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols

T. Taniguchi, E. Hayashi and T. Ono, Green Chem., 2002, 4, 595 DOI: 10.1039/B207215G

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