Issue 22, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and catalytic activity of three-coordinate zinc cations

Mark D. Hannant,a   Mark Schormanna  and  Manfred Bochmann*a  

* Corresponding authors

a Wolfson Materials and Catalysis Centre, School of Chemical Sciences, University of East Anglia, Norwich, UK
E-mail: m.bochmann@uea.ac.uk

Abstract

Reaction between DADZnR2 and either B(C6F5)3 or ZnR2 and [DADH][B(C6F5)4] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and ε-caprolactone [DAD = (MeC[double bond, length as m-dash]NC6H3Pri2-2,6)2].

Graphical abstract: Synthesis and catalytic activity of three-coordinate zinc cations

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Article information

DOI
https://doi.org/10.1039/B208165M
Article type
Communication
Submitted
20 Aug 2002
Accepted
08 Oct 2002
First published
16 Oct 2002

J. Chem. Soc., Dalton Trans., 2002, 4071-4073

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Synthesis and catalytic activity of three-coordinate zinc cations

M. D. Hannant, M. Schormann and M. Bochmann, J. Chem. Soc., Dalton Trans., 2002, 4071 DOI: 10.1039/B208165M

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