Issue 24, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

New group 15 compounds containing the 2,4,6-(CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands

Andrei S. Batsanov,a   Stéphanie M. Cornet,a   Keith B. Dillon,*a   Andrés E. Goeta,a   Paul Hazendonkb  and  Amber L. Thompsona  

* Corresponding authors

a Chemistry Department, University of Durham, South Road, Durham, UK

b Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive, Lethbridge, Alberta, Canada

Abstract

Several new P or As compounds containing the 2,4,6-(CF3)3C6H2 (Ar), 2,6-(CF3)2C6H3 (Ar′) and/or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised, and characterised by multinuclear NMR spectroscopy and (for all isolated compounds) elemental analysis. The crystal and molecular structures of ArPBr21, Ar2PCl 2, Ar″2PCl 3, Ar″2PBr 4, Ar′Ar″AsCl 5, Ar′Ar″AsBr 6 and Ar′Ar″AsH 7 have been determined by single-crystal X-ray diffraction. A particularly interesting feature of these structures is close contacts between ortho-fluorines and the P or As atoms, as observed previously in Ar′Ar″PCl and Ar2AsCl.

Graphical abstract: New group 15 compounds containing the 2,4,6-(CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands

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Article information

DOI
https://doi.org/10.1039/B207327G
Article type
Paper
Submitted
25 Jul 2002
Accepted
02 Oct 2002
First published
11 Nov 2002

J. Chem. Soc., Dalton Trans., 2002, 4622-4628

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New group 15 compounds containing the 2,4,6-(CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands

A. S. Batsanov, S. M. Cornet, K. B. Dillon, A. E. Goeta, P. Hazendonk and A. L. Thompson, J. Chem. Soc., Dalton Trans., 2002, 4622 DOI: 10.1039/B207327G

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