Synthesis, structure, DFT calculations, and full vibrational analysis of the prototypical thioformaldehyde complex mer-[W(CO)3(Me2PC2H4PMe2)(η2-SCH2)]†
Abstract
Reaction of PPN[W(CO)3(dmpe)(SH)] 2 (PPN = Ph3PNPPh3, dmpe = Me2PC2H4PMe2) with aqueous