The formation of an imidozirconium compound by migration of the imido group from phosphorus to zirconium†
Abstract
The η3/η1-bis(tert-butylamido)cyclodiphosph(III)azane zirconium chloride (η3-L)(η1-LH)ZrCl [1; L = (PNtBu)2(NtBu)2] has been synthesized from the reaction of NtBu{(NtBu)2PPNtBu}{K·(η6-C7H8)}·0.5C7H8] (2). The molecular structures of 1 and 2 have been determined by