Issue 6, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Unusual C–H bond activation—aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster†

Sergey P. Tunik,*a   Irina A. Balova,*a   Maxim E. Borovitov,a   Ebbe Nordlander,b   Matti Haukkac  and  Tapani A. Pakkanenc  

* Corresponding authors

a Department of Chemistry, St. Petersburg University, Universitetskii pr., 26, St. Petersburg, Staryi Peterhof, 198504, Russian Federation
E-mail: stunik@st1323.spb.edu

b Inorganic Chemistry, Center for Chemistry and Chemical Engineering, Lund University Box 124, SE-221 00 Lund, Sweden
E-mail: Ebbe.Nordlander@inorg.lu.se

c Department of Chemistry, University of Joensuu, P.O. Box 111, FIN-80101 Joensuu, Finland
E-mail: Tapani.Pakkanen@joensuu.fi

Abstract

Reactions of the triosmium cluster [HOs3(CO)10(η1:η1-OC4H2CCH3)] with a series of aromatic aldehydes under mild conditions result in condensation of the ligand methyl group with the aldehyde C[double bond, length as m-dash]O moiety to give typical aldol condensation products.

Graphical abstract: Unusual C–H bond activation—aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster

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Article information

DOI
https://doi.org/10.1039/B200707J
Article type
Communication
Submitted
18 Jan 2002
Accepted
29 Jan 2002
First published
11 Feb 2002

J. Chem. Soc., Dalton Trans., 2002, 827-828

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Unusual C–H bond activation—aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster

S. P. Tunik, I. A. Balova, M. E. Borovitov, E. Nordlander, M. Haukka and T. A. Pakkanen, J. Chem. Soc., Dalton Trans., 2002, 827 DOI: 10.1039/B200707J

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