Unusual C–H bond activation—aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster†
Abstract
Reactions of the triosmium cluster [HOs3(CO)10(η1:η1-OC4H2CCH3)] with a series of aromatic
* Corresponding authors
a
Department of Chemistry, St. Petersburg University, Universitetskii pr., 26, St. Petersburg, Staryi Peterhof, 198504, Russian Federation
E-mail:
stunik@st1323.spb.edu
b
Inorganic Chemistry, Center for Chemistry and Chemical Engineering, Lund University Box 124, SE-221 00 Lund, Sweden
E-mail:
Ebbe.Nordlander@inorg.lu.se
c
Department of Chemistry, University of Joensuu, P.O. Box 111, FIN-80101 Joensuu, Finland
E-mail:
Tapani.Pakkanen@joensuu.fi
Reactions of the triosmium cluster [HOs3(CO)10(η1:η1-OC4H2CCH3)] with a series of aromatic
S. P. Tunik, I. A. Balova, M. E. Borovitov, E. Nordlander, M. Haukka and T. A. Pakkanen, J. Chem. Soc., Dalton Trans., 2002, 827 DOI: 10.1039/B200707J
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