Issue 6, 2002

Zinc(ii) complexes of tetrapodal ligands derived from tetra-substituted 1,n-diaminoalcohols

Abstract

Dinuclear zinc(II) complexes have been prepared from one non-symmetric and two symmetric compartmental ligands in which the pendant arms, bearing pyridyl and phenolic functions, are bridged by spacers derived from 1,n-diaminoalcohols. The X-ray crystal structures of four complexes [Zn2L1(OAc)](ClO4)2·CH3OH (1a), [Zn2L1(OAc)](BPh4)2·6H2O (2a), [Zn2L2(OAc)](PF6)2 (4a) and [Zn2L3(OAc)] ·2.5H2O·1.5CH3OH (8a) are reported.

Graphical abstract: Zinc(ii) complexes of tetrapodal ligands derived from tetra-substituted 1,n-diaminoalcohols

Supplementary files

Article information

Article type
Paper
Submitted
09 Nov 2001
Accepted
08 Jan 2002
First published
21 Feb 2002

J. Chem. Soc., Dalton Trans., 2002, 925-930

Zinc(II) complexes of tetrapodal ligands derived from tetra-substituted 1,n-diaminoalcohols

H. Adams, D. Bradshaw and D. E. Fenton, J. Chem. Soc., Dalton Trans., 2002, 925 DOI: 10.1039/B110264H

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