Issue 4, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Supramolecular structure of {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 based on tetrametallic organometallic building blocks constructed from a multitopic tris(pyrazolyl)methaneligand

Daniel L. Reger,*a   Radu F. Semeniuca  and  Mark D. Smitha  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA
E-mail: reger@mail.chem.sc.edu
Fax: +1 803 777 9521
Tel: +1 803 777 2587

Abstract

The compound {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 forms a 3D sinusoidal architecture with 16 × 7 Å channels organized by π–π stacking and weak C–H⋯F hydrogen bonds.

Graphical abstract: Supramolecular structure of {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 based on tetrametallic organometallic building blocks constructed from a multitopic tris(pyrazolyl)methane ligand

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Article information

DOI
https://doi.org/10.1039/B110095E
Article type
Communication
Submitted
05 Nov 2001
Accepted
21 Jan 2002
First published
28 Jan 2002

J. Chem. Soc., Dalton Trans., 2002, 476-477

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Supramolecular structure of {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 based on tetrametallic organometallic building blocks constructed from a multitopic tris(pyrazolyl)methane ligand

D. L. Reger, R. F. Semeniuc and M. D. Smith, J. Chem. Soc., Dalton Trans., 2002, 476 DOI: 10.1039/B110095E

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