Unusual selective substitution of triply bridging carbonylligands for GaCp* in Rh6(CO)16. Synthesis and structural characterization of the Rh6(μ3-CO)4 − x(μ3-GaCp*)x(CO)12 clusters, x = 1–4†
Abstract
Reactions of hexanuclear rhodium clusters with GaCp* (Cp* = C5Me5) result in unusual substitution of face bridging CO