Platinum(iv)-mediated hydrolysis of nitriles giving metal-bound iminols
Abstract
The platinum(IV) complexes cis/trans-[PtCl4(MeCN)2] and trans-[PtCl4(EtCN)2] react smoothly and under mild conditions with
* Corresponding authors
a
Department of Chemistry, St. Petersburg State University, Universitetsky Pr. 2, 198504 Stary Petergof, Russian Federation
E-mail:
kukushkin@VK2100.spb.edu
b
Department of Chemistry, P.O. Box 111, Joensuu, FIN-80101, Finland
E-mail:
Matti.Haukka@Joensuu.Fi
c
Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisbon, Portugal
E-mail:
pombeiro@ist.utl.pt
The platinum(IV) complexes cis/trans-[PtCl4(MeCN)2] and trans-[PtCl4(EtCN)2] react smoothly and under mild conditions with
K. V. Luzyanin, M. Haukka, N. A. Bokach, M. L. Kuznetsov, V. Yu. Kukushkin and A. J. L. Pombeiro, J. Chem. Soc., Dalton Trans., 2002, 1882 DOI: 10.1039/B108327A
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