Laser spectroscopy of 1,2,3,4-tetrahydro-1-naphthol·ROH (R = H, CH3) clusters

D. Scuderi; A. Paladini; M. Satta; D. Catone; A. Filippi; S. Piccirillo; M. Speranza; A. Giardini Guidoni

doi:10.1039/B201347A

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Laser spectroscopy of 1,2,3,4-tetrahydro-1-naphthol·ROH (R = H, CH₃) clusters†

D. Scuderi,^ab A. Paladini,^a M. Satta,^c D. Catone,^a A. Filippi,^b S. Piccirillo,^d M. Speranza^b and A. Giardini Guidoni*^ac

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* Corresponding authors

^a Dipartimento di Chimica, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma, Italy
E-mail: anna.giardini@uniroma1.it
Fax: +39 06 490 324

^b Facoltà di Farmacia, Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma, Italy

^c CNR-IMIP (sezione Istituto Materiali Speciali), Tito Scalo (Pz), Italy

^d Università di Roma “Tor Vergata”Dipartimento di Scienze e Tecnologie Chimiche, Via della Ricerca Scientifica, Rome, Italy

Abstract

Wavelength and mass selected resonant enhanced multi-photon ionization (REMPI) spectroscopy is an excellent tool for characterising molecular clusters. Mass selected resonant two photon ionisation (R2PI) spectra of the S₁ ← S₀ transition of 1,2,3,4-tetrahydro-1-naphthol (T_R) and their complexes with solvent molecules such as water (W) and methanol (MeOH) have been recorded after a supersonic molecular beam expansion. Spectra have been analysed with the aid of ab initio molecular orbital calculations conducted at the B3LYP/6-31G** level of the theory.

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Article information

DOI: https://doi.org/10.1039/B201347A
Article type: Paper
Submitted: 06 Feb 2002
Accepted: 23 Apr 2002
First published: 16 May 2002

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Phys. Chem. Chem. Phys., 2002,4, 2806-2810

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Laser spectroscopy of 1,2,3,4-tetrahydro-1-naphthol·ROH (R = H, CH₃) clusters

D. Scuderi, A. Paladini, M. Satta, D. Catone, A. Filippi, S. Piccirillo, M. Speranza and A. Giardini Guidoni, Phys. Chem. Chem. Phys., 2002, 4, 2806 DOI: 10.1039/B201347A

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