Issue 58, 2002
From the journal:

CrystEngComm

An engineered N–H⋯π interaction: crystal structure of 4-tritylbenzamide–p-xylene (2∶1)†

C. Malla Reddy,a   Ashwini Nangia,*a   Chi-Keung Lamb  and  Thomas C. W. Mak*b  

* Corresponding authors

a School of Chemistry, University of Hyderabad, Hyderabad 500 046, India
E-mail: ansc@uohyd.ernet.in

b Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China
E-mail: tcwmak@cuhk.edu.hk

Abstract

The title host–guest crystal structure is designed to contain an N–H⋯π interaction. The crystal structure is stabilised by an N–H⋯O hydrogen-bonded amide dimer and weak N–H⋯π and C–H⋯O hydrogen bonds. The phenyl rings of triphenylmethyl groups interact via the edge-to-face herringbone T-motif.

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Article information

DOI
https://doi.org/10.1039/B202297D
Article type
Paper
Submitted
05 Mar 2002
Accepted
03 May 2002
First published
17 Jul 2002

CrystEngComm, 2002,4, 323-325

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An engineered N–H⋯π interaction: crystal structure of 4-tritylbenzamide–p-xylene (2∶1)

C. M. Reddy, A. Nangia, C. Lam and T. C. W. Mak, CrystEngComm, 2002, 4, 323 DOI: 10.1039/B202297D

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