Charge transfer complexes of 2,4,6-tricyano-s-triazine with tetrathiafulvalene (TTF) and N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD)

Rico E. Del Sesto; Mark Botoshansky; Menahem Kaftory; Atta M. Arif; Joel S. Miller

doi:10.1039/B201648F

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Rico E. Del Sesto,^a Mark Botoshansky,^b Menahem Kaftory,^b Atta M. Arif^a and Joel S. Miller*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Utah, Salt Lake City, UT, USA
E-mail: jsmiller@chem.utah.edu

^b Department of Chemistry, Technion-Israel Institute of Technology, Haifa, Israel

Abstract

Reaction of 2,4,6-tricyano-s-triazine (TCT) with tetrathiafulvalene (TTF) and N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) leads to 1∶1 charge transfer complexes. The crystal structures of the TTF[TCT], as well as the decomposition product due to hydrolysis of the [TMPD][TCT], i.e. [HTMPD]⁺[2,4-dicyano-6-oxy-s-triazine]⁻, are reported and spectroscopically characterized.

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Article information

DOI: https://doi.org/10.1039/B201648F
Article type: Paper
Submitted: 13 Feb 2002
Accepted: 08 Mar 2002
First published: 26 Mar 2002

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CrystEngComm, 2002,4, 117-120

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