Issue 24, 2002
From the journal:

Chemical Communications

Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure†

Haidoo Kwen,a   Sean Tomlinson,a   Eric A. Maatta,*a   Céline Dablemont,b   René Thouvenot,b   Anna Proust*b  and  Pierre Gouzerhb  

* Corresponding authors

a Department of Chemistry, Kansas State University, Manhattan, Kansas 66506-3701, USA
E-mail: eam@ksu.edu
Fax: +1 785 532 6666
Tel: +1 785 532 6687

b Chimie Inorganique et Matériaux Moléculaires, UMR 7071, Université Pierre et Marie Curie, 4 Place Jussieu, Paris Cedex 05, France
E-mail: proust@ccr.jussieu.fr
Fax: +33 1 44 27 38 41
Tel: +33 1 44 27 30 34

Abstract

Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVI[triple bond, length as m-dash]N]3+, [ReVI[triple bond, length as m-dash]N]3+ and [ReVII[triple bond, length as m-dash]N]4+ fragments, respectively, into the framework of a Keggin-type heteropolyanion.

Graphical abstract: Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B209173A
Article type
Communication
Submitted
19 Sep 2002
Accepted
22 Oct 2002
First published
07 Nov 2002

Chem. Commun., 2002, 2970-2971

Permissions

Request permissions

Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

H. Kwen, S. Tomlinson, E. A. Maatta, C. Dablemont, R. Thouvenot, A. Proust and P. Gouzerh, Chem. Commun., 2002, 2970 DOI: 10.1039/B209173A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements