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Issue 24, 2002
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A very bulky carboxylic perchlorotriphenylmethyl radical as a novel ligand for transition metal complexes. A new spin frustrated metal system

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Abstract

Reaction of a carboxylic perchlorotriphenylmethyl radical with Cu2(O2CCH3)4·2H2O using different molar ratios yields two different transition metal complexes with strong intramolecular antiferromagnetic interactions, which in the case of complex 2 follows a butterfly spin frustrated model.

Graphical abstract: A very bulky carboxylic perchlorotriphenylmethyl radical as a novel ligand for transition metal complexes. A new spin frustrated metal system

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Article information


Submitted
09 Sep 2002
Accepted
05 Nov 2002
First published
19 Nov 2002

Chem. Commun., 2002, 2958-2959
Article type
Communication

A very bulky carboxylic perchlorotriphenylmethyl radical as a novel ligand for transition metal complexes. A new spin frustrated metal system

D. Maspoch, D. Ruiz-Molina, K. Wurst, C. Rovira and J. Veciana, Chem. Commun., 2002, 2958
DOI: 10.1039/B208759F

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