Issue 24, 2002
From the journal:

Chemical Communications

A very bulky carboxylic perchlorotriphenylmethyl radical as a novel ligand for transition metal complexes. A new spin frustrated metal system

Daniel Maspoch,a   Daniel Ruiz-Molina,a   Klaus Wurst,b   Concepció Rovira*a  and  Jaume Veciana*a  

* Corresponding authors

a Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Bellaterra, Catalonia, Spain
E-mail: vecianaj@icmab.es
Fax: 34 93 5805729
Tel: 34 93 580 1853

b Institut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 52a, Austria

Abstract

Reaction of a carboxylic perchlorotriphenylmethyl radical with Cu2(O2CCH3)4·2H2O using different molar ratios yields two different transition metal complexes with strong intramolecular antiferromagnetic interactions, which in the case of complex 2 follows a butterfly spin frustrated model.

Graphical abstract: A very bulky carboxylic perchlorotriphenylmethyl radical as a novel ligand for transition metal complexes. A new spin frustrated metal system

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Article information

DOI
https://doi.org/10.1039/B208759F
Article type
Communication
Submitted
09 Sep 2002
Accepted
05 Nov 2002
First published
19 Nov 2002

Chem. Commun., 2002, 2958-2959

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A very bulky carboxylic perchlorotriphenylmethyl radical as a novel ligand for transition metal complexes. A new spin frustrated metal system

D. Maspoch, D. Ruiz-Molina, K. Wurst, C. Rovira and J. Veciana, Chem. Commun., 2002, 2958 DOI: 10.1039/B208759F

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