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Issue 22, 2002
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A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O–H bond

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Abstract

Mo(PMe3)6 reacts with 2,6-Ph2C6H3OH to give the η6-arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3 which exhibits a non-classical Mo⋯H–OAr hydrogen bond; DFT calculations indicate that the hydrogen bonding interaction facilitates oxidative addition of the O–H bond to give [η61-C6H5C6H3(Ph)O]Mo(PMe3)2H.

Graphical abstract: A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O–H bond

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Publication details

The article was received on 05 Sep 2002, accepted on 25 Sep 2002 and first published on 11 Oct 2002


Article type: Communication
DOI: 10.1039/B208678F
Citation: Chem. Commun., 2002,0, 2644-2645

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    A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O–H bond

    T. Hascall, M. Baik, B. M. Bridgewater, J. H. Shin, D. G. Churchill, R. A. Friesner and G. Parkin, Chem. Commun., 2002, 0, 2644
    DOI: 10.1039/B208678F

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