Issue 22, 2002
From the journal:

Chemical Communications

A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O–H bond†

Tony Hascall,a   Mu-Hyun Baik,a   Brian M. Bridgewater,a   Jun Ho Shin,a   David G. Churchill,a   Richard A. Friesner*a  and  Gerard Parkin*a  

* Corresponding authors

a Department of Chemistry, Columbia University, New York, New York, USA
E-mail: parkin@chem.columbia.edu
Fax: 212 932 1289
Tel: 212 854 8247

Abstract

Mo(PMe3)6 reacts with 2,6-Ph2C6H3OH to give the η6-arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3 which exhibits a non-classical Mo⋯H–OAr hydrogen bond; DFT calculations indicate that the hydrogen bonding interaction facilitates oxidative addition of the O–H bond to give [η6,η1-C6H5C6H3(Ph)O]Mo(PMe3)2H.

Graphical abstract: A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O–H bond

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Article information

DOI
https://doi.org/10.1039/B208678F
Article type
Communication
Submitted
05 Sep 2002
Accepted
25 Sep 2002
First published
11 Oct 2002

Chem. Commun., 2002, 2644-2645

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A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O–H bond

T. Hascall, M. Baik, B. M. Bridgewater, J. H. Shin, D. G. Churchill, R. A. Friesner and G. Parkin, Chem. Commun., 2002, 2644 DOI: 10.1039/B208678F

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