Issue 20, 2002
From the journal:

Chemical Communications

Triple C–H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex†

Vladimir F. Kuznetsov,a   Alan J. Loughb  and  Dmitry G. Gusev*a  

* Corresponding authors

a Wilfrid Laurier University, Department of Chemistry, Waterloo, Ontario, Canada
E-mail: dgoussev@wlu.ca
Fax: +1 (519) 746-0677
Tel: +1 (519) 884-1970

b University of Toronto, Department of Chemistry, X-Ray laboratory, Toronto, Ontario, Canada
E-mail: alough@chem.utoronto.ca

Abstract

This communication reports the preparation of a novel trans-chelating diphosphine, 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane, that undergoes triple C–H activation in reaction with [RuCl2(p-cymene)]2 to give a chiral square-pyramidal 16-electron carbene complex of ruthenium.

Graphical abstract: Triple C–H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex

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Article information

DOI
https://doi.org/10.1039/B208325F
Article type
Communication
Submitted
28 Aug 2002
Accepted
08 Sep 2002
First published
24 Sep 2002

Chem. Commun., 2002, 2432-2433

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Triple C–H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex

V. F. Kuznetsov, A. J. Lough and D. G. Gusev, Chem. Commun., 2002, 2432 DOI: 10.1039/B208325F

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