Issue 21, 2002
From the journal:

Chemical Communications

Linkage isomerism and C–H activation in an ytterbium(ii) tetraphenylborate

Glen B. Deacon*a  and  Craig M. Forsytha  

* Corresponding authors

a School of Chemistry, Monash University, Clayton 3800, Australia
E-mail: glen.deacon@sci.monash.edu.au
Fax: +61 3 9905 4597
Tel: +61 3 9905 4568

Abstract

Reaction of [Yb{N(SiMe3)2}2(thf)2] with [Me3NH][BPh4] (1∶1) in PhMe gives a mixture of products including [Yb{N(SiMe3)2}(thf)BPh4] (1), which exhibits two structural forms, and [Yb{N(SiMe3)SiMe2CH2BPh3}(thf)2] (2) with an unusual silylamidoborate ligand.

Graphical abstract: Linkage isomerism and C–H activation in an ytterbium(ii) tetraphenylborate

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Article information

DOI
https://doi.org/10.1039/B208149K
Article type
Communication
Submitted
20 Aug 2002
Accepted
10 Sep 2002
First published
30 Sep 2002

Chem. Commun., 2002, 2522-2523

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Linkage isomerism and C–H activation in an ytterbium(II) tetraphenylborate

G. B. Deacon and C. M. Forsyth, Chem. Commun., 2002, 2522 DOI: 10.1039/B208149K

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