Issue 19, 2002

Capture of di-protonated [2.2.2]cryptand in the cavity of two p-sulfonated calixarenes as part of 2-D bi-layer lanthanide coordination polymers

Abstract

Treating p-sulfonatocalix[4]arene with lanthanide ions, Ln3+ (Ln = Ce, Nd, Sm and Eu), in the presence of [2.2.2]cryptand results in a 2-D bi-layer coordination polymer with axially elongated diprotonated cryptand in the cavity of two p-sulfonatocalix[4]arenes.

Graphical abstract: Capture of di-protonated [2.2.2]cryptand in the cavity of two p-sulfonated calixarenes as part of 2-D bi-layer lanthanide coordination polymers

Supplementary files

Article information

Article type
Communication
Submitted
08 Aug 2002
Accepted
23 Aug 2002
First published
11 Sep 2002

Chem. Commun., 2002, 2216-2217

Capture of di-protonated [2.2.2]cryptand in the cavity of two p-sulfonated calixarenes as part of 2-D bi-layer lanthanide coordination polymers

S. J. Dalgarno and C. L. Raston, Chem. Commun., 2002, 2216 DOI: 10.1039/B207922B

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