Issue 22, 2002
From the journal:

Chemical Communications

cis-Stereoselective nickel-catalyzed cyclization/alkylation and arylation reactions of allenyl-aldehydes and -ketones with organozinc reagents†

Suk-Ku Kang*a  and  Seok-Keun Yoona  

* Corresponding authors

a Department of Chemistry and Lab for Metal-Catalyzed Reactions, Sungkyunkwan University, Suwon, Korea

Abstract

Highly stereoselective alkylative and arylative cyclization reactions of allenyl-aldehydes and -ketones with organozinc reagents occur efficiently in the presence of catalytic Ni(COD)2 to afford cis-fused homoallylic cyclopentanols.

Graphical abstract: cis-Stereoselective nickel-catalyzed cyclization/alkylation and arylation reactions of allenyl-aldehydes and -ketones with organozinc reagents

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Article information

DOI
https://doi.org/10.1039/B207620A
Article type
Communication
Submitted
06 Aug 2002
Accepted
19 Sep 2002
First published
28 Oct 2002

Chem. Commun., 2002, 2634-2635

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cis-Stereoselective nickel-catalyzed cyclization/alkylation and arylation reactions of allenyl-aldehydes and -ketones with organozinc reagents

S. Kang and S. Yoon, Chem. Commun., 2002, 2634 DOI: 10.1039/B207620A

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