2D 4.82 Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead(II) nitrate

Shuang-Yi Wan; Jian Fan; Taka-aki Okamura; Hui-Fang Zhu; Xing-Mei Ouyang; Wei-Yin Sun; Norikazu Ueyama

doi:10.1039/B207568G

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2D 4.8² Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead(ii) nitrate†

Shuang-Yi Wan,^a Jian Fan,^a Taka-aki Okamura,^b Hui-Fang Zhu,^a Xing-Mei Ouyang,^a Wei-Yin Sun*^a and Norikazu Ueyama^b

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* Corresponding authors

^a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China
E-mail: sunwy@nju.edu.cn
Fax: +86 25 3314502
Tel: +86 25 3593485

^b Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan

Abstract

Reaction of nanometer-sized tripodal ligand 2,4,6-tris[4-(imidazol-1-ylmethyl)phenyl]-1,3,5-triazine (timpt) with lead(II) nitrate affords a novel polycatenated structure containing three interpenetrating 4.8² networks, in which the lead(II) atom has a hemidirected coordination geometry and a stereochemically active lone pair of electrons.

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Article information

DOI: https://doi.org/10.1039/B207568G
Article type: Communication
Submitted: 02 Aug 2002
Accepted: 18 Sep 2002
First published: 03 Oct 2002

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Chem. Commun., 2002, 2520-2521

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2D 4.8² Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead(II) nitrate

S. Wan, J. Fan, T. Okamura, H. Zhu, X. Ouyang, W. Sun and N. Ueyama, Chem. Commun., 2002, 2520 DOI: 10.1039/B207568G

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Chemical Communications