Thioepoxide formation by ring closure of allylthiyl radicals—a novel rearrangement of allylic thionitrites
Abstract
Tertiary allylic thionitrites undergo thermal rearrangement to α,β-episulfide
* Corresponding authors
a
University College London, Christopher Ingold Laboratories, 20 Gordon Street, London, UK
E-mail:
w.b.motherwell@ucl.ac.uk
Fax: +44 20 7679 7524
Tel: +44 20 7679 7533
b Institut de Chimie des Substances Naturelles, CNRS, Avenue de la Terrasse, Cedex, Gif-sur-Yvette, France
Tertiary allylic thionitrites undergo thermal rearrangement to α,β-episulfide
M. Cavero, W. B. Motherwell, P. Potier and J. Weibel, Chem. Commun., 2002, 2394 DOI: 10.1039/B207252C
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