Issue 18, 2002
From the journal:

Chemical Communications

First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [{Cu(1,2-pn)2}7{V16O38(H2O)}2]·4H2O

Bi-Zhou Lin*ab  and  Shi-Xiong Liua  

* Corresponding authors

a Department of Chemistry, Fuzhou University, Fuzhou, P. R. China

b Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, P. R. China
E-mail: bzlin@hqu.edu.cn

Abstract

The hydrothermal reaction of V2O5, Cu(CH3COO)2·H2O, 1,2-diaminopropane and [N(CH3)4]OH yields the novel three-dimensional open-framework solid [{Cu(1,2-pn)2}7{V16O38(H2O)}2]·4H2O constructed from the new mixed-valence [V16O38(H2O)]7− clusters interconnected through μ2-[Cu(1,2-pn)2]2+ groups.

Graphical abstract: First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [{Cu(1,2-pn)2}7{V16O38(H2O)}2]·4H2O

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Article information

DOI
https://doi.org/10.1039/B206880J
Article type
Communication
Submitted
15 Jul 2002
Accepted
13 Aug 2002
First published
22 Aug 2002

Chem. Commun., 2002, 2126-2127

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First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [{Cu(1,2-pn)2}7{V16O38(H2O)}2]·4H2O

B. Lin and S. Liu, Chem. Commun., 2002, 2126 DOI: 10.1039/B206880J

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