Issue 18, 2002

Transfer of alk-1-enyl group from boron to aluminium: a novel way to prepare (E)-alk-1-enyldiisobutylalanes

Abstract

Treatment of (E)-alk-1-enyldicyclohexylboranes 1 with diisobutylaluminium hydride (DIBAL-H) in the presence of hex-1-ene at room temperature results in transfer of the alk-1-enyl group from boron to aluminium to give (E)-alk-1-enyldiisobutylalanes 2 with retention of configuration at the double bond.

Graphical abstract: Transfer of alk-1-enyl group from boron to aluminium: a novel way to prepare (E)-alk-1-enyldiisobutylalanes

Article information

Article type
Communication
Submitted
05 Jul 2002
Accepted
13 Aug 2002
First published
27 Aug 2002

Chem. Commun., 2002, 2146-2147

Transfer of alk-1-enyl group from boron to aluminium: a novel way to prepare (E)-alk-1-enyldiisobutylalanes

M. Hoshi and K. Shirakawa, Chem. Commun., 2002, 2146 DOI: 10.1039/B206541J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements