Issue 17, 2002
From the journal:

Chemical Communications

Assembly of polyaminesviaamino acids from three components using cobalt(iii) template methodology

Gilles Laval,a   William Clegg,a   Christopher G. Crane,b   Anders Hammershøi,c   Alan M. Sargesonb  and  Bernard T. Golding*a  

* Corresponding authors

a Department of Chemistry, Bedson Building, University of Newcastle upon Tyne, Newcastle upon Tyne, UK
E-mail: b.t.golding@ncl.ac.uk
Fax: +44(0) 191-222-6929
Tel: +44(0) 191-222-6647

b Research School of Chemistry, Australian National University, Canberra, Australia
E-mail: sargeson@rsc.anu.edu.au
Fax: (+612) 61253216
Tel: (+61) 6125-3160

c Department of Chemistry, University of Copenhagen, Universitetsparken 5, Copenhagen, Denmark
E-mail: anders@kiku.dk
Fax: (+45) 3532-0133
Tel: (+45) 3532-0110

Abstract

A versatile and efficient template synthesis has been developed to synthesise novel polyamines [e.g. rac-N3-(3-aminopropyl)butane-1,3-diamine, isospermidine 1] via amino acids [e.g. (2R,4S/2S,4R)-N4-(3-aminopropyl)-2,4-diaminopentanoic acid] using cobalt(III) to assemble the three precursor components in a biomimetic manner.

Graphical abstract: Assembly of polyamines via amino acids from three components using cobalt(iii) template methodology

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Article information

DOI
https://doi.org/10.1039/B206462F
Article type
Communication
Submitted
03 Jul 2002
Accepted
19 Jul 2002
First published
02 Aug 2002

Chem. Commun., 2002, 1874-1875

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Assembly of polyamines via amino acids from three components using cobalt(III) template methodology

G. Laval, W. Clegg, C. G. Crane, A. Hammershøi, A. M. Sargeson and B. T. Golding, Chem. Commun., 2002, 1874 DOI: 10.1039/B206462F

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