C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(ii) complexes†
Abstract
Alkyl chlorides R–Cl are dehalogenated by HSiMe2Ph in the presence of catalytic amounts of the complex [(κ2-P,N)-Ph2PCH2CH2NMe2]PtMeCl to give R–H and ClSiMe2Ph.
* Corresponding authors
a Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9/165, A-1060, Wien, Austria
Alkyl chlorides R–Cl are dehalogenated by HSiMe2Ph in the presence of catalytic amounts of the complex [(κ2-P,N)-Ph2PCH2CH2NMe2]PtMeCl to give R–H and ClSiMe2Ph.
F. Stöhr, D. Sturmayr and U. Schubert, Chem. Commun., 2002, 2222 DOI: 10.1039/B205405A
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