Issue 13, 2002

Enantiomerically enriched [2-2H]-isopentenyl alcohol from (E)-2-methylbut-2-ene-1,4-diol by an asymmetric retro-ene reaction

Abstract

A sample of [2-2H]-isopentenyl alcohol containing 72% of the (S)-enantiomer has been prepared via pyrolysis of a C-1′ deuterated form of the 1-tetra-O-acetyl-β-D-glucoside of (E)-2-methylbut-2-ene-1,4-diol.

Graphical abstract: Enantiomerically enriched [2-2H]-isopentenyl alcohol from (E)-2-methylbut-2-ene-1,4-diol by an asymmetric retro-ene reaction

Article information

Article type
Communication
Submitted
11 Apr 2002
Accepted
02 May 2002
First published
27 May 2002

Chem. Commun., 2002, 1388-1389

Enantiomerically enriched [2-2H]-isopentenyl alcohol from (E)-2-methylbut-2-ene-1,4-diol by an asymmetric retro-ene reaction

J. Giner and D. Arigoni, Chem. Commun., 2002, 1388 DOI: 10.1039/B203559F

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