Issue 10, 2002
From the journal:

Chemical Communications

Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes†

Silvio Aime,*a   Alessandro Barge,a   Andrei S. Batsanov,d   Mauro Botta,c   Daniela Delli Castelli,a   Franco Fedeli,b   Armando Mortillaro,a   David Parker*d  and  Horst Puschmannd  

* Corresponding authors

a Dipartimento di Chimica IFM, Università di Torino, Via P. Giuria I-10125, Torino, Italy

b Laboratorio Integrato di Metodologie Avanzate, Bioindustry Park Canavese, Via Ribes 5, Colleretto Giacosa (TO), Italy

c Dipartimento di Scienze e Tecnologie Avanzate, Università del Piemonte Orientale “Amedeo Avogadro”, Corso T. Borsalino, 54, Alessandria, Italy

d Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: david.parker@durham.ac.uk

Abstract

The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.

Graphical abstract: Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes

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Article information

DOI
https://doi.org/10.1039/B202862J
Article type
Communication
Submitted
21 Mar 2002
Accepted
04 Apr 2002
First published
19 Apr 2002

Chem. Commun., 2002, 1120-1121

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Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes

S. Aime, A. Barge, A. S. Batsanov, M. Botta, D. D. Castelli, F. Fedeli, A. Mortillaro, D. Parker and H. Puschmann, Chem. Commun., 2002, 1120 DOI: 10.1039/B202862J

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