Issue 13, 2002
From the journal:

Chemical Communications

A three-dimensional nanoporous flexible network of ‘square-planar’ copper(ii) centres with an unusual topology†

Lucia Carlucci,a   Nicola Cozzi,b   Gianfranco Ciani,*b   Massimo Moret,c   Davide M. Proserpiob  and  Silvia Rizzatob  

* Corresponding authors

a Dipartimento di Biologia Strutturale e Funzionale, Università dell’Insubria, Varese, Italy

b Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università di Milano, Milano, Italy
E-mail: davide@csmtbo.mi.cnr.it

c Dipartimento di Scienza dei Materiali, Università di Milano-Bicocca, Milano, Italy

Abstract

Cu(II) triflate reacts with 4,4′-bipyridyl in different solvents to yield the new 3D network [Cu(4,4′-bipy)2(CF3SO3)2], based on pseudo-square planar nodes and consisting of crossing layers of large rhombic meshes (22 × 22 Å) fused together into an overall (two-fold interpenetrated) array, with a topology unprecedented within coordination frames and an interesting nanoporous behaviour.

Graphical abstract: A three-dimensional nanoporous flexible network of ‘square-planar’ copper(ii) centres with an unusual topology

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B202588D
Article type
Communication
Submitted
14 Mar 2002
Accepted
08 May 2002
First published
23 May 2002

Chem. Commun., 2002, 1354-1355

Permissions

Request permissions

A three-dimensional nanoporous flexible network of ‘square-planar’ copper(II) centres with an unusual topology

L. Carlucci, N. Cozzi, G. Ciani, M. Moret, D. M. Proserpio and S. Rizzato, Chem. Commun., 2002, 1354 DOI: 10.1039/B202588D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements