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Issue 13, 2002
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A three-dimensional nanoporous flexible network of ‘square-planar’ copper(ii) centres with an unusual topology

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Abstract

Cu(II) triflate reacts with 4,4′-bipyridyl in different solvents to yield the new 3D network [Cu(4,4′-bipy)2(CF3SO3)2], based on pseudo-square planar nodes and consisting of crossing layers of large rhombic meshes (22 × 22 Å) fused together into an overall (two-fold interpenetrated) array, with a topology unprecedented within coordination frames and an interesting nanoporous behaviour.

Graphical abstract: A three-dimensional nanoporous flexible network of ‘square-planar’ copper(ii) centres with an unusual topology

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Article information


Submitted
14 Mar 2002
Accepted
08 May 2002
First published
23 May 2002

Chem. Commun., 2002, 1354-1355
Article type
Communication

A three-dimensional nanoporous flexible network of ‘square-planar’ copper(II) centres with an unusual topology

L. Carlucci, N. Cozzi, G. Ciani, M. Moret, D. M. Proserpio and S. Rizzato, Chem. Commun., 2002, 1354
DOI: 10.1039/B202588D

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