Issue 8, 2002
From the journal:

Chemical Communications

Productive trapping of NAD-type radicals. Non-biomimetic reduction of pyridinium salts†

Rodolfo Lavilla,*ab   M. Carmen Bernabeu,ab   Enric Brillas,c   Inés Carranco,ab   José Luis Díaz,ab   Nereida Llorente,a   Marta Rayoa  and  Alessandro Spadaa  

* Corresponding authors

a Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona, Av. Joan XXIII sn, Barcelona, Spain
E-mail: lavilla@farmacia.far.ub.es;
Fax: +34 934024539;
Tel: +34 934024540

b Parc Científic de Barcelona, Baldiri Reixac 10-12, Barcelona, Spain

c Departament de Química Física, University of Barcelona, Martí i Franquès 1, Barcelona, Spain

Abstract

One-electron reduction of pyridinium salts (NAD+ analogues) generates dihydropyridyl radicals which may then be engaged in radical addition processes to regioselectively form γ-substituted dihydropyridines.

Graphical abstract: Productive trapping of NAD-type radicals. Non-biomimetic reduction of pyridinium salts

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Article information

DOI
https://doi.org/10.1039/B201813F
Article type
Communication
Submitted
19 Feb 2002
Accepted
01 Mar 2002
First published
19 Mar 2002

Chem. Commun., 2002, 850-851

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Productive trapping of NAD-type radicals. Non-biomimetic reduction of pyridinium salts

R. Lavilla, M. C. Bernabeu, E. Brillas, I. Carranco, J. L. Díaz, N. Llorente, M. Rayo and A. Spada, Chem. Commun., 2002, 850 DOI: 10.1039/B201813F

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