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Issue 12, 2002
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Solid supported fluoronitroaryl triazenes as immobilized and convertible Sanger reagents – synthesis and SNAr reactions towards a novel preparation of 1-alkyl-5-nitro-1H-benzotriazoles

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Abstract

Synthesis of novel fluoronitroaryl triazenes in liquid phase and on solid support have been described; mild displacement of the fluoride ion with various nucleophiles provides access to substituted arenes which in turn can be cleaved to provide a unique access to 1-alkyl-5-nitro-1H-benzotriazole.

Graphical abstract: Solid supported fluoronitroaryl triazenes as immobilized and convertible Sanger reagents – synthesis and SNAr reactions towards a novel preparation of 1-alkyl-5-nitro-1H-benzotriazoles

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Publication details

The article was received on 11 Feb 2002, accepted on 25 Mar 2002 and first published on 17 May 2002


Article type: Communication
DOI: 10.1039/B201489K
Citation: Chem. Commun., 2002,0, 1296-1297
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    Solid supported fluoronitroaryl triazenes as immobilized and convertible Sanger reagents – synthesis and SNAr reactions towards a novel preparation of 1-alkyl-5-nitro-1H-benzotriazoles

    M. E. P. Lormann, C. H. Walker, M. Es-Sayed and S. Bräse, Chem. Commun., 2002, 0, 1296
    DOI: 10.1039/B201489K

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