Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(ii)-pyrazolato cyclic trimer
Abstract
A triangular homoleptic complex, [Pd(μ-3-Ph-pz)2]3, is prepared by the stepwise formation of an open-chain trimer and subsequent ring-closure; D3 molecular symmetry results from the one-directional arrangement of the unsymmetrically substituted pyrazolato