Issue 10, 2002
From the journal:

Chemical Communications

2-(1,3-Dithiolan-2-ylidene)-5-(1,3-dithian-2-ylidene)- 1,3,4,6-tetrathiapentalene(DHDA-TTP), a hybrid of BDH-TTP and BDA-TTP, and its metallic cation-radical salts†

Jun-ichi Yamada,*a   Maki Watanabe,a   Takashi Toita,a   Hiroki Akutsu,a   Shin′ichi Nakatsuji,a   Hiroyuki Nishikawa,b   Isao Ikemotob  and  Koichi Kikuchi*b  

* Corresponding authors

a Department of Material Science, Graduate School and Faculty of Science, Himeji Institute of Technology, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan
E-mail: yamada@sci.himeji-tech.ac.jp
Fax: +81(0)791-58-0164
Tel: +81(0)791-58-0162

b Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan

Abstract

The synthesis and electrochemical properties of the DHDA-TTP donor, a hybrid of 2,5-bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene (BDH-TTP) and 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene (BDA-TTP), has been investigated, and its ability to form metallic cation-radical salts is elucidated.

Graphical abstract: 2-(1,3-Dithiolan-2-ylidene)-5-(1,3-dithian-2-ylidene)- 1,3,4,6-tetrathiapentalene(DHDA-TTP), a hybrid of BDH-TTP and BDA-TTP, and its metallic cation-radical salts

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Article information

DOI
https://doi.org/10.1039/B200556P
Article type
Communication
Submitted
16 Jan 2002
Accepted
11 Apr 2002
First published
25 Apr 2002

Chem. Commun., 2002, 1118-1119

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2-(1,3-Dithiolan-2-ylidene)-5-(1,3-dithian-2-ylidene)- 1,3,4,6-tetrathiapentalene(DHDA-TTP), a hybrid of BDH-TTP and BDA-TTP, and its metallic cation-radical salts

J. Yamada, M. Watanabe, T. Toita, H. Akutsu, S. Nakatsuji, H. Nishikawa, I. Ikemoto and K. Kikuchi, Chem. Commun., 2002, 1118 DOI: 10.1039/B200556P

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